Alkene Metathesis in Organic Synthesis (Topics in - download pdf or read online

Alkene Metathesis in Organic Synthesis (Topics in - download pdf or read online

By Alois Fuerstner

ISBN-10: 3540642544

ISBN-13: 9783540642541

The great development in olefin metathesis completed over the last decade can rarely be overvalued. as a result of the improvement of a brand new iteration of good outlined and high-performance organometallic catalysts, this response is swiftly evolving into the most flexible instruments for complex natural chemistry, common product synthesis, effective chemical creation and polymer sciences. Written via many of the prime specialists during this box, this monograph intends to familiarize the reader with the main interesting advancements and frontiers during this flourishing box of chemistry study.

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Additional info for Alkene Metathesis in Organic Synthesis (Topics in Organometallic Chemistry) (Vol 1)

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57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 75. 76. 77. 78. 79. 80. 81. Richard R. Schrock Peters JU, Blechert S (1997) Chem Commun 1983 Feldman J, Schrock RR (1991) Prog Inorg Chem 39:1 Buhro WE, Chisholm MH (1987) Adv Organometal Chem 27:311 Breslow DS (1993) Progress in Polymer Science 18:1141 Streck R (1988) J Mol Catal 46:305 Nugent WA, Feldman J, Calabrese JC (1995) J Am Chem Soc 117:8992 Xu Z, Johannes CW, Houri AF, La DS, Cogan DA, Hofilena GE, Hoveyda AH (1997) J Am Chem Soc 119:10302 Parkin G, Bunel E, Burger BJ, Trimmer MS, van Asselt A, Bercaw JE (1987) J Molec Catal 41:21 Freundlich JS, Schrock RR, Davis WM (1996) J Am Chem Soc 118:3643 Freundlich JS, Schrock RR, Davis WM (1996) Organometallics 15:2777 Edwards DS, Biondi LV, Ziller JW, Churchill MR, Schrock RR (1983) Organometallics 2:1505 van der Schaff PA, Hafner A, Mühlebach A (1996) Angew Chem Int Ed Engl 35:1845 Johnson LK, Frey M, Ulibarri TA, Virgil SC, Grubbs RH, Ziller JW (1993) J Am Chem Soc 115:8167 Sharp PR, Schrock RR (1979) J Organometal Chem 171:43 Wengrovius JH, Schrock RR (1982) Organometallics 1:148 Binger P, Müller P, Benn R, Mynott R (1989) Angew Chem 101:647 Johnson LK, Grubbs RH, Ziller JW (1993) J Am Chem Soc 115:8130 de la Mata FJ, Grubbs RH (1996) Organometallics 15:577 de la Mata FJ (1996) J Organomet Chem 525:183 Wu Z, Wheeler DR, Grubbs RH (1992) J Am Chem Soc 114:146 Murdzek JS, Schrock RR (1988) In: (ed) Carbyne complexes.

0]decadiene product 28. 0] compound 32 is formed exclusively, because the cyclization cascade is then triggered at the other end of the substrate. Note that in both examples trisubstituted olefins are obtained by means of a ruthenium based metathesis catalyst [20]! The idea of determining the site of initiation via the substitution pattern of the olefin has also been used by Blechert et al. during the course of a stereocontrolled RCM process (Scheme 10). Again, the reaction starts most likely at the terminal olefin site in 33 independent of whether 1 or 24 is used as catalyst; however, due to the different coordination geometries of ruthenium and molybdenum, the evolving carbene reacts with either diastereotopic olefin attached to 50 A.

66 References . . . . . . . . . . . . . . . . . 70 1 Introduction The metathesis activity of various simple ruthenium compounds has already been discerned during early studies on the ring opening metathesis polymerization (ROMP) of norbornene and other cycloalkene substrates [1, 2]. A real breakthrough, however, was achieved when Grubbs et al. reported in the early 1990s that ruthenium-carbene complexes of the general type 1 are highly active single component (pre)catalysts for any kind of olefin metathesis reaction (Fig.

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